(Solution) - Hexahelicene seems a poor candidate for optical activity because all -(2025 Original AI-Free Solution)

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Academic Level: Undergrad. (yrs 3-4)

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Hexahelicene seems a poor candidate for optical activity because all its carbon atoms are sp2 hybrids and presumably flat. Nevertheless, hexahelicene has been synthesized and separated into enantiomers. Its optical rotation is enormous [?]D 3700o. Explain why hexahelicene is optically active, and speculate as to why the rotation is so large.

Hexahelicene seems a poor candidate for optical activity because all