(Solution) - Nitrogen is present in many pharmaceutical drugs as described in -(2025 Original AI-Free Solution)

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Nitrogen is present in many pharmaceutical drugs, as described in "A Word About . . . Morphine and Other Nitrogen-Containing Drugs" (pages 405-406). Varenicline is a drug inspired by morphine and is a prescription medication used to aid in smoking cessation.

What is your prediction of the pKa values for the conjugate acids of each of the nitrogens in varenicline?